Synthesis and Luminescence Spectra of Copper-Containing Monoclinic PbCd2B6O12-Based Materials

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Abstract

New copper-containing borates with the general formula PbCd2–xB6O12:xCu2+ have been prepared by solid-state reactions and characterized by X-ray diffraction and IR spectroscopy. A continuous series of substitutional solid solutions isostructural with monoclinic PbCd2B6O12 (sp. gr. P21/n) has been shown to exist in the range 0 < x ≤ 0.08. Replacing cadmium atoms by copper atoms, which are smaller in size, leads to a linear decrease in unit-cell parameters across the solid solution series. The IR spectroscopy and X-ray diffraction data suggest the presence of BO3 and BO4 anions in the structure of the borates. The thermoluminescence intensity has been measured as a function of activator content in the range 25–400°C. The thermoluminescence intensity in the borates increases with activator content, reaching a maximum at x = 0.06, and decreases at higher doping levels. The powder borates studied here can be used as a key component of new luminescence materials.

About the authors

T. N. Khamaganova

Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, 670047, Ulan-Ude, Buryat Republic, Russia

Author for correspondence.
Email: khama@binm.ru
Россия, 670047, Улан-Удэ, ул. Сахьяновой, 6

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