Thermal Stability and Luminescence Properties of Cerium-Containing Tricalcium Phosphate

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Cerium-containing tricalcium phosphate (TCP, Ca3(PO4)2) nanopowders with the whitlockite structure have been prepared via precipitation from solution. After heat treatment at 1300°C, the materials contained 0, 0.07, 0.18, and 0.39 wt % cerium, which corresponded to х = 0, 0.0025, 0.006, and 0.013 in the general formula Ca3 – хCe2х/3(PO4)2. The thermal stability of β-TCP has been shown to increase with increasing cerium content. The synthesized cerium-containing TCP powders show luminescence properties under excitation at wavelengths from 270 to 320 nm, with a peak emission wavelength from 360 to 390 nm, characteristic of Ce3+ luminescence. Varying the percentage of cerium in the materials and heat treatment temperature causes the emission spectrum to shift.

Sobre autores

Yu. Nikitina

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

Email: nyo.94@yandex.ru
Россия, 119334, Москва, Ленинский пр., 49

N. Petrakova

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

Email: petrakova.nv@mail.ru
Россия, 119334, Москва, Ленинский пр., 49

S. Kozyukhin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

Email: komlev@mail.ru
Россия, 119991, Москва, Ленинский пр., 31

V. Sirotinkin

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

Email: komlev@mail.ru
Россия, 119334, Москва, Ленинский пр., 49

A. Konovalov

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

Email: komlev@mail.ru
Россия, 119334, Москва, Ленинский пр., 49

Yu. Kargin

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

Email: komlev@mail.ru
Россия, 119334, Москва, Ленинский пр., 49

S. Barinov

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

Email: komlev@mail.ru
Россия, 119334, Москва, Ленинский пр., 49

V. Komlev

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

Autor responsável pela correspondência
Email: komlev@mail.ru
Россия, 119334, Москва, Ленинский пр., 49

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Declaração de direitos autorais © Ю.О. Никитина, Н.В. Петракова, С.А. Козюхин, В.П. Сиротинкин, А.А. Коновалов, Ю.Ф. Каргин, С.М. Баринов, В.С. Комлев, 2023