Ternary Intermetallic Compounds R26(RuxIn1 – x)17 (R = Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Lu), Pr21Ru8.2In5 and Gd6Ru2In with High Content of Rare Earth Elements

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

In the R–Ru–In (R—rare earth element) systems in the area with a high content of rare-earth elements (>60 at %), a number of isostructural compounds R26(RuxIn1 – x)17 (R = Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Lu) were found, which crystallize in a tetragonal cell (P4/mbm) with the Sm26(Co0.65Ga0.35)17 structure type, as well as Pr21Ru8.2In5 compounds in a tetragonal cell (I4/mcm) with the Y3Rh2 structure type and Gd6Ru2In in a rhombic cell (Immm) with the Ho6Co2Ga structure type. The samples were prepared by arc-melting the stoichiometric quantities of elementary components. The structures were determined by single-crystal X-ray diffraction and refined by the Rietveld method using powder patterns. Compounds R26(RuxIn1–x)17 (R = Dy, Ho, Er, Tm, Lu) exist in the homogeneity range 0.28 < x < 0.47. All crystal structures of the obtaining compounds are based on a frame from atoms of rare earth elements, inside which are smaller in size atoms of ruthenium and indium. A general fragment of all the considered structures are columns of various lengths from InR8 tetragonal prisms and RuR8 tetragonal antiprisms conjugated by mutual bases. The new compounds have a congruent melting pattern.

About the authors

D. V. Sedelnikov

Moscow State University, 119991, Moscow, Russia

Email: sedelnikov.denis.96@mail.ru
Россия, 119991, Москва, Ленинские горы, 1

J. M. Kurenbaeva

Moscow State University, 119991, Moscow, Russia

Email: sedelnikov.denis.96@mail.ru
Россия, 119991, Москва, Ленинские горы, 1

E. V. Murashova

Moscow State University, 119991, Moscow, Russia

Author for correspondence.
Email: sedelnikov.denis.96@mail.ru
Россия, 119991, Москва, Ленинские горы, 1

References

  1. Petrovic C., Pagliuso P.G., Hundley M.F., Movshovich R., Sarrao J.L., Thompson J.D., Fisk Z., Monthoux P. Heavy-Fermion Superconductivity in CeCoIn5 at 2.3 K // J. Phys.: Condens. Matter. 2001. V. 13. № 17. P. 337–342. https://doi.org/10.1088/0953-8984/13/17/103
  2. Petrovic C., Movshovich R., Jaime M., Pagliuso P.G., Hundley M.F., Sarrao J.L., Fisk Z., Thompson J.D. A New Heavy-Fermion Superconductor CeIrIn5: a Relative of the Cuprates? // Europhys. Lett. 2001. V. 53. № 3. P. 354–359. https://doi.org/10.1209/epl/i2001-00161-8
  3. Moshopoulou E.G., Fisk Z., Sarrao J.L., Thompson J.D. Crystal Growth and Intergrowth Structure of the New Heavy Fermion Materials CeIrIn5 and CeRhIn5 // J. Solid State Chem. 2001. V. 158. № 1. P. 25–33. https://doi.org/10.1006/jssc.2000.9052
  4. Canepa F., Napoletano M., Fornasini M.L., Merlo F. Structure and Magnetism of Gd2Co2Ga, Gd2Co2Al and Gd14Co3In2.7 // J. Alloys Compd. 2002. V. 345. № 1–2. P. 42–49. https://doi.org/10.1016/S0925-8388(02)00395-X
  5. Kalychak Y.M., Zaremba V.I., Pöttgen R., Lukachuk M., Hoffmann R.-D. Rare Earth-Transition Metal-Indides // Gschneider K.A., Pecharsky V.K., Bünzli J.-C. Handbook on the Physics and Chemistry of Rare Earths. Amsterdam. Elsevier, 2005. V. 34. № 218. P. 1–133.
  6. Калычак Я.М., Заремба В.И., Степьен-Дамм Дж., Галаджун Я.В., Аксельруд Л.Г. Кристаллическая структура Sm12Ni6In и родственных соединений // Кристаллография. 1998. Т. 43. С. 17–20. https://doi.org/10.1134/1.170758
  7. Заремба В.И., Калычак Я.М., Завали П.Ю. Кристаллическая структура R14Co2In3 // Кристаллография. 1992. Т. 37. № 2. С. 352–355.
  8. Lukachuk M., Galadzhun Y.V., Zaremba R.I., Dzevenko M.V., Kalychak Y.M., Zaremba R.I., Rodewald U.Ch., Pöttgen R. New Rare Earth Metal-Rich Indides RE14Ni3In3 (RE = Sc, Y, Gd–Tm, Lu) – Synthesis and Crystal Chemistry // J. Solid State Chem. 2005. V. 178. № 9. P. 2724−2733. https://doi.org/10.1016/j.jssc.2005.06.021
  9. Zaremba R.I., Pöttgen R. Rare Earth Metal-Rich Indides RE14Rh3−xIn3 (RE=Y, Dy, Ho, Er, Tm, Lu) // J. Solid State Chem. 2007. V. 180. № 9. P. 2452–2458. https://doi.org/10.1016/j.jssc.2007.06.005
  10. Lukachuk M., Kalychak Y.M., Dzevenko M., Pöttgen R. On the Crystal Chemistry of Tm2Ni1.896(4)In, Tm2.22(2)Ni1.81(1)In0.78(2), Tm4.83(3)Ni2In1.17(3), and Er5Ni2In // J. Solid State Chem. 2005. V. 178. № 4. P. 1247–1253. https://doi.org/10.1016/j.jssc.2004.11.023
  11. Gulay N.L., Kösters J., Reimann M.-K., Kalychak Y.M., Pöttgen R. Lu26T17–xInx (T = Rh, Ir, Pt) – First Indium Intermetallics with Sm26Co11Ga6-Type Structure // Z. Naturforsch., B: Chem. Sci. 2022. V. 77. № 10. P. 735–741. https://doi.org/10.1515/znb-2022-0111
  12. Ярмолюк Я.П., Гринь Ю.Н., Олеш О.М. Кристаллическая структура соединений R26GaxCo17–x (R = La, Ce, Pr, Nd, Sm) и R26GaxNi17–x (R = Ce, Pr, Nd, Sm) // Кристаллография. 1980. Т. 25. № 2. С. 248–255.
  13. Tursina A.I., Cherviakov S.G., Noël H., Chernyshev V.V., Seropegin Y.D. Lanthanum Ruthenium Indide, La21Ru9+xIn5–x (x = 1.2) // Acta Crystallogr., Sect. E: Struct. Rep. Online. 2010. V. 66. P. i40. https://doi.org/10.1107/S1600536810014509
  14. Moreau J.M., Paccard D., Parthe E. The Tetragonal Crystal Structure of R3Rh2 Compounds with R = Gd, Tb, Dy, Ho, Er, Y // Acta Crystallogr., Sect. B: Struct. Sci. 1976. V. 32. P. 1767–1771. https://doi.org/10.1107/S0567740876006365
  15. Шаблинская К.В., Грибанова В.А., Марушина Е.В., Куренбаева Ж.М., Мурашова Е.В. Тройные интерметаллические соединения церия со структурой La23Ni7Mg4 // Матер. всерос. науч. конф. с международным участием “II Байкальский материаловедческий форум”. Т. 1. (29 июня–5 июля) Россия: БНЦ СО РАН Улан-Удэ, 2015. С. 136–137.
  16. Tappe F., Schwickert C., Linsiger S., Pöttgen R. New Rare Earth-Rich Aluminides and Indides with Cubic Gd4RhIn-Type Structure // Monatsh. Chem. 2011. V. 142. P. 1087–1095. https://doi.org/10.1007/s00706-011-0622-3
  17. Demchyna M., Belan B., Manyako M., Akselrud L., Gagor A., Dzevenko M., Kalychak Y. Phase Equilibria in the Dy–Fe–In System and Crystal Structure of Dy6Fe1.72In // Intermetallics. 2013. V. 37. P. 22–26. https://doi.org/10.1016/j.intermet.2013.01.010
  18. Мурашова Е.В., Куренбаева Ж.М. Синтез и кристаллическая структура новых тройных интерметаллидов системы Ce–Ru–Ga с известными структурными типами // Неорган. материалы. 2019. Т. 55. № 8. С. 833–840. https://doi.org/10.1134/S0002337X19080104
  19. STOE WINXPOW, Version 2.24. Stoe & Cie GmbH, Germany, Darmstadt, 2007.
  20. Rodriguez-Carvajal J. FULLPROF: a Program for Rietveld Refinement and Pattern Matching Analysis // Abstracts of the Satellite Meeting on Powder Diffraction of the XV Congress of the IUCr. Toulouse. 1990. P. 127.
  21. Roisnel T., Rodriguez-Carvajal J. Materials Science Forum // Proceedings of the European Powder Diffraction Conference (EPDIC7). 2000. P. 118.
  22. Sheldrick G.M. Crystal Structure Refinement with SHELXL // Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2015. V. 71. № 1. P. 3–8. https://doi.org/10.1107/S2053229614024218
  23. Sheldrick G.M. SADABS – Bruker Nonius Area Detector Scaling and Absorption Correction. Univesity of Göttingen, 2004.
  24. Brandenburg K. DIAMOND. Release 3.2k. Crystal Impact Gmbh, Bonn. 2014.
  25. De Kozak A., Samouel M., Erb A. Le Système DyF3–Dy2O3 // Rev. Chim. Miner. 1980. V. 17. P. 440–444.
  26. De Kozak A., Samouel M., Chrétien A. Les Systèmes GdF3–MF (M = K, Rb, Cs) et GdF3–Gd2O3 // Rev. Chim. Miner. 1973. V. 10. P. 259–271.
  27. Le Roy J., Moreau J.M., Paccard D., Parthé E. Rare Earth-Iridium Compounds with Pu5Rh3 and Y3Rh2 Structure Types: Members of a New Structural Series with Formula R5n+6T3n+5 // J. Less-Common Met. 1980. V. 76. № 1–2. P. 131–135. https://doi.org/10.1016/0022-5088(80)90016-8
  28. Tappe F., Schappacher F.M., Langer T., Schellenberg I., Pöttgen R. Solid Solutions RE16Rh11–xZx (RE = La, Ce, Pr, Nd, Sm; Z = Ga, Zn, Cd, In, Sn, Sb, Pb, Bi) – Centrosymmetric n = 2 Variants of Parthé’s Homologous Series A5n+6B3n+5 // Z. Naturforsch., B: Chem. Sci. 2012. V. 67. P. 594–604. https://doi.org/10.5560/znb.2012-0070
  29. Aronsson B. The Crystal Structure of Mo5Si3 and W5Si3 // Acta Chem. Scand. 1955. V. 9. № 7. P. 1107–1110.
  30. Moreau J.M., Paccard D., Parthé E. The Tetragonal Crystal Structure of R3Rh2 Compounds with R = Gd, Tb, Dy, Ho, Er, Y // Acta Crystallogr., Sect. B: Struct. Sci. 1976. V. 32. P. 1767–1771. https://doi.org/10.1107/S0567740876006365
  31. Leon-Escamilla E.A., Corbett J.D. Solid State Compounds with Tin-Tin Bonding. Yb36Sn23: A Novel Compound Containing Oligomeric Tin Anions // Inorg. Chem. 1999. V. 38. № 4. P. 738–743. https://doi.org/10.1021/ic980861x
  32. Emsley J. The Elements. Oxford: Oxford University Press, 1999. P. 255.

Supplementary files


Copyright (c) 2023 Д.В. Седельников, Ж.М. Куренбаева, Е В. Мурашова