Technological Features of the Preparation of Zinc Ferrite Using a Sol–Gel Process

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Abstract

We have studied the formation of the structure of zinc ferrite using sol–gel synthesis in the presence of a number of organic templates: polyacrylamide, citric acid, sucrose, and urea. The synthesized materials were characterized by X-ray diffraction and electron microscopy, and we estimated the crystallite size by the Scherrer method. The results demonstrate that the formation of the spinel structure is most complete if polyacrylamide or citric acid is used as an organic template. In the case of citric acid, we obtained materials with the smallest crystallite size. The samples obtained in the presence of sucrose or urea were not single-phase. We carried out thermodynamic assessment of the processes in question. The results of this study make it possible to knowingly choose an organic precursor for the synthesis of microcrystalline spinel ferrites.

About the authors

N. P. Shabel’skaya

Platov State Polytechnic University, 346428, Novocherkassk, Rostov oblast, Russia; Southern Federal University, 344006, Rostov-on-Don, Russia

Email: nina_shabelskaya@mail.ru
Россия, 346428, Ростовская обл., Новочеркасск, ул. Просвещения, 132; Россия, 344006, Ростов-на-Дону, ул. Б. Садовая, 105/42

M. A. Egorova

Platov State Polytechnic University, 346428, Novocherkassk, Rostov oblast, Russia

Email: nina_shabelskaya@mail.ru
Россия, 346428, Ростовская обл., Новочеркасск, ул. Просвещения, 132

A. M. Radzhabov

Platov State Polytechnic University, 346428, Novocherkassk, Rostov oblast, Russia

Email: nina_shabelskaya@mail.ru
Россия, 346428, Ростовская обл., Новочеркасск, ул. Просвещения, 132

V. A. Ul’yanova

Platov State Polytechnic University, 346428, Novocherkassk, Rostov oblast, Russia

Email: nina_shabelskaya@mail.ru
Россия, 346428, Ростовская обл., Новочеркасск, ул. Просвещения, 132

Yu. A. Gaidukova

Platov State Polytechnic University, 346428, Novocherkassk, Rostov oblast, Russia

Author for correspondence.
Email: nina_shabelskaya@mail.ru
Россия, 346428, Ростовская обл., Новочеркасск, ул. Просвещения, 132

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Copyright (c) 2023 Н.П. Шабельская, М.А. Егорова, А.М. Раджабов, В.А. Ульянова, Ю.А. Гайдукова