Synthesis of Fe/TaON/β-Si3N4/β-Si3Al3O3N5 Composites for Photocatalytic Degradation of Chloramphenicol in Water

L. N. Skvortsova; Скворцова Л. Н.; K. I. Kazantseva; Казанцева К. И.; K. A. Bolgaru; Болгару К. А.; A. A. Reger; Регер А. А.; I. A. Artyukh; Артюх И. А.; K. A. Dychko; Дычко К. А.

doi:10.31857/S0002337X23030120

Synthesis of Fe/TaON/β-Si3N4/β-Si3Al3O3N5 Composites for Photocatalytic Degradation of Chloramphenicol in Water

Authors: Skvortsova L.N.¹, Kazantseva K.I.¹, Bolgaru K.A.², Reger A.A.², Artyukh I.A.¹, Dychko K.A.¹
Affiliations:
1. National Research Tomsk State University, 634050, Tomsk, Russia
2. Tomsk Scientific Center, Siberian Branch, Russian Academy of Sciences, 634021, Tomsk, Russia
Issue: Vol 59, No 3 (2023)
Pages: 333-340
Section: Articles
URL: https://medjrf.com/0002-337X/article/view/668324
DOI: https://doi.org/10.31857/S0002337X23030120
EDN: https://elibrary.ru/YTVAKH
ID: 668324

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Fe/TaON/β-Si3N4/β-Si3Al3O3N5 metal–ceramic composites have been prepared via autowave combustion of ferrosilicoaluminum and metallic tantalum additions (0, 5, 10, and 15 wt %) in nitrogen. We have determined the phase composition of the composites and studied their morphological features and optical properties. Acid–base properties of the surface of the composites have been investigated and their adsorptive and photocatalytic activity for chloramphenicol degradation has been assessed under UV and visible light illumination. The composites have been shown to be highly effective in oxidative degradation of chloramphenicol (98%) under illumination with visible light.

Keywords

self-propagating synthesis, metal–ceramic composites, tantalum oxynitride

References

Ribeiro A.R., Nunes O.C., Pereira Manuel F.R. et al. An Overview on the Advanced Oxidation Processes Applied for the Treatment of Water Pollutants Defined in the Recently launched Directive 2013/39/EU // Environ. Int. 2015. V. 75. P. 33–51. https://doi.org/10.1016/j.envint.2014.10.027
Huang J., Li R., Li D. et al. One-Step Synthesis of Phosphorus/oxygen Co-Doped g-C3N4/Anatase TiO2 Zscheme Photocatalyst for Significantly Enhanced Visible-Light Photocatalysis Degradation of Enrofloxacin // J. Hazard. Mater. 2020. V. 386. P. 121634.
Florent M., Giannakoudakis D.A., Bandosz T. Detoxification of Mustard Gas Surrogate on ZnO2/g-C3N4 Composites: Effect of Surface Features’ Synergy and Day-night Photocatalysis // Appl. Catal., B. 2020. V. 272. https://doi.org/10.1016/j.apcatb.2020.119038
Ершов Д.С., Беспрозванных Н.В., Синельщикова О.Ю. Синтез, фотокаталитические и электрофизические свойства керамических материалов в системе PbO–Bi2O3–Fe2O3 // Журн. неорган. химии. 2022. Т. 67. № 1. С. 118–126. https://doi.org/10.31857/S0044457X22010032
Zhang P., Liu B., Li Yu. et al. Egg White-Mediated Synthesis and Application of Ag/CeO2 Photocatalyst for Enhanced Photocatalytic Activity under Visible Light Irradiation // Russ. J. Inorg. Chem. 2021. V. 66. № 14. P. 2036–2044.https://doi.org/10.1134/S0036023621140096
Орлов В.М., Седнева Т.А. Синтез и фотокаталитические характеристики мезопористого оксинитрида тантала // Перспективные материалы. 2017. № 1. С. 5–12.
Duan Li, Liang Zeng, Bin Li et al. Rapid Synthesis of Dielectric Tantalum-Based Oxynitrides // Mater. Des. 2020. V. 187. P. 108416. https://doi.org/10.1016/j.matdes.2019.108416
Fang C.M., Orhan E., de Wijs G.A., Hintzen H.T. The Electronic Structure of Tantalum (oxy)nitrides TaON and Ta3N5 // J. Mater. Chem. 2001. № 11. P. 1248–1252. https://doi.org/10.1039/B005751G
Qijie Jin, Bingxu Lu, Youchun Pan et al. Novel Porous Ceramic Sheet Supported Metal Reactors for Continuous-Flow Catalysis // Catal. Today. 2019. № 3. P. 324–332. https://doi.org/10.1016/j.cattod.2019.12.006
Sherstoboeva M.V., Bavykina A.V., Bolgaru K.A. et al. Metal-Ceramic Composites for Photocatalytic Oxidation of Diclofenac in Aqueous Solution // J. ChemistrySelect. 2020. № 5. P. 1912–1918. https://doi.org/10.1002/slct.201904010
Скворцова Л.Н., Болгару К.А., Шерстобоева М.В. и др. Деградация диклофенака в водных растворах в условиях совмещенного гомогенного и гетерогенного фотокатализа // ЖФХ. 2020. Т. 94. № 6. С. 926–931. https://doi.org/10.31857/S0044453720060242
Wadley S., Waite T.D. Fenton Processes-Advanced Oxidation Processes for Water and Wastewater Treatment. London: IWA Publishing, 2004. P. 111–135.
Нечипоренко А.П., Кудряшова А.И. Исследование кислотности твердых поверхностей методом рН-метрии // ЖПХ. 1987. Т. 60. № 9. С. 1957–1961.
Нечипоренко А.П. Донорно-акцепторные свойства поверхности твердофазных систем. Индикаторный метод. СПб: Лань, 2017. 2843 с.
Гриценко В.А. Электронная структура нитрида кремния // Успехи физических наук. 2012. Т. 182. № 5. С. 531–541. https://doi.org/10.3367/UFNr.0182.201205d.0531
Artukh I.A., Bolgaru K.A., Dychko K.A. et al. Hydrogen Production by Photocatalytic Degradation of Organic Substances Using Iron-Containing Metal-Ceramic Composites Under UV and Visible-Light Irradiation // J. ChemistrySelect. 2021. № 6. P. 10025–10032. https://doi.org/10.1002/slct.202102014
Cheng M., Zeng G., Huang D. et al. Hydroxyl Radicals Based Advanced Oxidation Processes (AOPs) for Remediation of Soils Contaminated with Organic Compounds: A review // Chem. Eng. J. 2016. V. 284. P. 582–598. https://doi.org/10.1016/j.cej.2015.09.001