Microwave Synthesis of Nickel-Based Catalysts for Selective Hydrogenation of Phenylacetylene to Styrene
- Authors: Zhuravleva V.S.1,2, Shesterkina A.A.3, Strekalova A.A.1, Kapustin G.I.1, Dunaev S.F.3, Kustov A.L.3
-
Affiliations:
- Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
- Russian Technological University MIREA
- Faculty of Chemistry, Moscow State University
- Issue: Vol 97, No 10 (2023)
- Pages: 1415-1420
- Section: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
- Submitted: 26.02.2025
- Published: 01.10.2023
- URL: https://medjrf.com/0044-4537/article/view/668639
- DOI: https://doi.org/10.31857/S004445372310028X
- EDN: https://elibrary.ru/PPNDUP
- ID: 668639
Cite item
Abstract
New nickel-containing catalysts based on the phyllosilicate phase have been obtained by microwave activation for efficient liquid-phase hydrogenation of a number of unsaturated compounds to olefins under relatively mild reaction conditions: T = 100–140°C, pH2 = 1.5 MPa, reaction time 1 h. A comparison of the synthesis methods showed that the best results with 90.1% selectivity of styrene formation at 89.6% conversion of phenylacetylene were obtained on the nickel catalyst prepared by microwave synthesis.
About the authors
V. S. Zhuravleva
Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences; Russian Technological University MIREA
Email: vickey.vi202@gmail.com
119991, Moscow, Russia; 119454, Moscow, Russia
A. A. Shesterkina
Faculty of Chemistry, Moscow State University
Email: vickey.vi202@gmail.com
119992, Moscow, Russia
A. A. Strekalova
Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
Email: vickey.vi202@gmail.com
119991, Moscow, Russia
G. I. Kapustin
Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
Email: vickey.vi202@gmail.com
119991, Moscow, Russia
S. F. Dunaev
Faculty of Chemistry, Moscow State University
Email: vickey.vi202@gmail.com
119992, Moscow, Russia
A. L. Kustov
Faculty of Chemistry, Moscow State University
Author for correspondence.
Email: vickey.vi202@gmail.com
119992, Moscow, Russia
References
- Yang K., Chen X., Guan J. et al. // Catal. Today. 2015. V. 246. P. 176.
- Molnár Á., Sárkány A., Varga V. // Mol. Cat. A. Chem. 2001. V. 173. P. 185.
- Bonrath W., Medlock J., Schütz J. et al. // Hydrogenation. 2012. P. 66.
- Kluwer A.M., Koblenz T.S., Jonishkeit T. et al. // Am. Chem. Soc. 2005. V. 127. P. 15470.
- Rahsepar M., Kim H. // J. Alloys Compd. 2015. V. 649. P. 1323.
- Redina E.A., Greish A.A., Mishin I.V. et al. // Catal. Today. 2015. V. 241. P. 246.
- Beletskaya I.P., Kustov L.M. // Russ. Chem. Rev. 2010. V. 79 (6). P. 441.
- Sels B.F., Kustov L.M. // Zeolites and Zeolite-like Materials 2016. P. 1.
- Manjunatha C., Ashoka S., Hari Krishna R. Chapter 1 – Microwave-assisted Green Synthesis of Inorganic Nanomaterials, Green Sustainable Process for Chemical and Environmental Engineering and Science. 2021. P. 1.
- Bian Z., Kawi S. // Catal. Today. 2020. V. 339. P. 3.
- Wang M.L., Ban X.Q., Xie L.Q. et al. // ACS Sustain. Chem. Eng. 2019. V. 7. P. 1989.
- Yu J., Yang Y.S., Chen L.F. et al. // Appl. Catal. B: Environ. 2020. V. 277. 119273.
- Wang Y.L.H. // Chem. Phys. Lett. 2020. V. 757. 137871.
- Aguilar-Tapia A., Delannoy L., Loui C. et al. // J. Catal. 2016. V. 344. P. 515.
- Narani A., Kannapu H.P.R., Natte K. et al. // Mol. Catal. 2020. V. 497. 111200.
- Kirichenko O., Kapustin G., Nissenbaum V. et al. // J. Therm. Anal. Calorim. 2018. V. 134. P. 233.
- Kirichenko O., Kapustin G., Nissenbaum V. et al. // J. Therm. Anal. Calorim. 2014. V. 118. P. 749.
- H. Liu, H. Wang, J. Shen, Y. Sun and Z. Liu // Applied Catalysis A: General, https://doi.org/10.1016/j.apcata.2007.12.006
