Fe- and Cu–Zn-Containing Catalysts Based on Natural Aluminosilicate Nanotubes and Zeolite H-ZSM-5 in the Hydrogenation of Carbon Dioxide

E. M. Smirnova; Смирнова Е. М.; N. D. Evdokimenko; Евдокименко Н. Д.; M. V. Reshetina; Решетина М. В.; N. R. Demikhova; Демихова Н. Р.; A. L. Kustov; Кустов А. Л.; S. F. Dunaev; Дунаев С. Ф.; V. A. Vinokurov; Винокуров В. А.; A. P. Glotov; Глотов А. П.

doi:10.31857/S0044453723070270

Fe- and Cu–Zn-Containing Catalysts Based on Natural Aluminosilicate Nanotubes and Zeolite H-ZSM-5 in the Hydrogenation of Carbon Dioxide

Autores: Smirnova E.M.¹, Evdokimenko N.D.², Reshetina M.V.¹, Demikhova N.R.¹, Kustov A.L.², Dunaev S.F.², Vinokurov V.A.¹, Glotov A.P.¹^,2
Afiliações:
1. Gubkin State University of Oil and Gas
2. Faculty of Chemistry, Moscow State University
Edição: Volume 97, Nº 7 (2023)
Páginas: 952-959
Seção: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
##submission.dateSubmitted##: 27.02.2025
##submission.datePublished##: 01.07.2023
URL: https://medjrf.com/0044-4537/article/view/668696
DOI: https://doi.org/10.31857/S0044453723070270
EDN: https://elibrary.ru/SMHNKL
ID: 668696

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Resumo

Iron- and Cu–Zn-containing carbon dioxide hydrogenation catalysts based on natural aluminosilicate nanotubes and zeolite H-ZSM-5 are synthesized. Their textural and acidic properties are studied via low-temperature nitrogen adsorption–desorption, temperature-programmed desorption of ammonia, temperature-programmed reduction of hydrogen, and elemental analysis. The effect the temperatures of the reaction have on the conversion of CO2 and distribution of its product is studied. Catalysts based on aluminosilicate halloysite nanotubes exhibit methanol and С2–С4 hydrocarbon selectivities of 88 and 16%, respectively.

Palavras-chave

halloysite, methanol, carbon dioxide, olefins, H-ZSM-5, Fe, Cu–Zn

Bibliografia

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