Heterogeneous-catalytic reaction of hydrogenation-dehydrogenation of aromatic compounds as the basis of accumulation, storage, and production of chemically pure hydrogen

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The quality of hydrogen released from naphthenic substrates (bicyclohexyl, ortho-, meta-, and para-isomers of perhydroterphenyl) as a result of catalytic dehydrogenation over 3% Pt/C (sibunit) is studied as a key criterion for the high degree of regeneration and recyclization of hydrogen storage systems. It is shown that chemically pure hydrogen without impurities of methane and carbon oxides can be obtained by the dehydrogenation of liquid organic hydrogen carriers (LOHC) if the initial aromatic hydrocarbons and the naphthenic substrates obtained from them were previously thoroughly thermally treated before the hydrogenation and dehydrogenation reactions, respectively, in an inert gas.

Full Text

Restricted Access

About the authors

А. N. Каlenchuk

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: akalenchuk@yandex.ru
Russian Federation, 119992, Moscow; 119991, Moscow

V. I. Bogdan

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
Russian Federation, 119992, Moscow; 119991, Moscow

L. M. Kustov

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
Russian Federation, 119992, Moscow; 119991, Moscow

He Teng

Dalian Institute of Chemical Physics

Email: akalenchuk@yandex.ru
China, Dalian

References

  1. Reuß M., Grube Th., Robinius M. et al. // Appl. Energy. 2017. V. 200. P. 290.
  2. Preuster P., Alekseev A., Wasserscheid P. // Annu. Rev. Chem. Biomol. Eng. 2017. V. 8. P. 445.
  3. Rao P.Ch., Yoon M. // Energies. 2020. V. 13. P. 6040.
  4. Makaryan I.A., Sedova I.V., Maksimov A.L. // Rus. J. Appl. Chem. 2020. V. 93. N. 12. P. 1815.
  5. Jorschick H., Geißelbrecht M., Eßl M. et al. // Int. J. Hydrogen Energy. 2020. V. 45. P. 14897.
  6. Дубинин А.М., Финк А.В, Кагарманов Г.Р. // Промышленная энергетика. 2007. № 5. С. 32.
  7. Хоффман Е. Энерготехнологическое использование угля. М.: Энергоиздат, 1983. 328 C.
  8. Иоффе В.Б. Основы производства водорода. Л.: Гостехиздат, 1960. 427 C.
  9. Bulgarin A., Jorschick H., Preuster P. et al. // Int. J. Hydrogen Energy. 2020. V. 45. P. 712.
  10. Якименко Л.М., Модылевская И.Д., Ткачек З.Я. Электролиз воды. М.: Химия. 1970. 318 C.
  11. Tremel A., Wasserscheid P., Baldauf M., Hammer T. // Int. J. Hydrogen Energy. 2015. V. 40. P. 11457.
  12. Cipriani G., Di Dio V., Genduso F., La Cascia D. // Int. J. Hydrogen Energy. 2014. V. 39. P. 8482.
  13. Sekine Y., Higo T. // Topics in Catalysis. 2021. V. 64. P. 470.
  14. Cho J.-Y., Kim H., O J.-E., Park B.Y. // Catalysts. 2021. V. 11. P. 14971525.
  15. Кустов Л.М., Каленчук А.Н., Богдан В.И. // Успехи химии. 2020. Т. 89. С. 897.
  16. Ren J., Musyoka N.M., Langmi H.W. et al. // Int. J. Hydrogen Energy. 2017. V. 42. P. 289.
  17. Kalenchuk A.N., Bogdan V.I., Dunaev S.F., Kustov L.M. // Int. J. Hydrogen Energy. 2018. V. 43. P. 6191.
  18. Каленчук А.Н., Богдан В.И., Кустов Л.М. // Журн.физ. химии. 2015. Т. 89. С. 20.
  19. Кalenchuk А.N., Bogdan V.I., Dunaev S.F., Кustov L.М. // Fuel. 2020. V. 280. № 15. P. 118625.
  20. Кalenchuk А.N., Кustov L.М. // Molecules. 2022. V. 27. № 7. P. 2236.
  21. Кustov L.M., Кalenchuk A.N., Dunaev S.F., Bogdan V.I. // Mendeleev Commun. 2019. V. 29. P. 25.
  22. Цырульников П.Г., Иост К.Н., Шитова Н.Б., Темерев В.Л. // Катал. хим. нефтехим. пром. 2016. Т. 16. С. 20.
  23. Каленчук А.Н., Маслаков К.И., Богдан Т.В. и др. // Изв. АН. 2021. T. 2. 323.
  24. Goethel P.J., Yang R.T. // J. Catal. 1988. V. 111. P. 220.
  25. Bogdan V.I., Kalenchuk A.N., Chernavsky P.A. et al. // Int. J. Hydrogen Energy. 2021. V. 46. № 1. P. 1.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Fig. 1. Chromatogram of gaseous products of the dehydrogenation reaction.

Download (93KB)
Indexing metadata

Copyright (c) 2025 Russian Academy of Sciences