Oxygen-containing compounds in polydimethylsilanes and -carbosilanes
- 作者: Filippov А.М.1, Gorodetskaya A.V.1, Prokhortseva V.V.1, Zhigalov D.V.1, Zhuk D.A.1, Storozhenko P.A.1
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隶属关系:
- State Research Institute of Chemistry and Technology of Organoelement Compounds
- 期: 卷 94, 编号 4 (2024)
- 页面: 528-542
- 栏目: Articles
- URL: https://medjrf.com/0044-460X/article/view/667427
- DOI: https://doi.org/10.31857/S0044460X24040071
- EDN: https://elibrary.ru/EBFLJW
- ID: 667427
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详细
An analysis of fractions extracted from polydimethylsilanes, as well as distillates obtained during the synthesis of poly(oligo)carbosilanes was carried out. By the methods of gel permeation chromatography and chromatography-mass spectrometry, the range of molecular weights in extracts and distillates, the composition and structure of compounds, as well as the sequence of their retention times on the chromatographic column were determined. It was established that the compounds extracted from polydimethylsilanes are low molecular weight cycles containing methylsilane and/or methylsiloxane units. In distillates, compared with extracts, the number of low molecular weight compounds containing individual or mixed methylsilane, carbosilane and siloxane units increases.
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作者简介
А. Filippov
State Research Institute of Chemistry and Technology of Organoelement Compounds
编辑信件的主要联系方式.
Email: amphil@yandex.ru
俄罗斯联邦, Moscow, 105118
A. Gorodetskaya
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: amphil@yandex.ru
俄罗斯联邦, Moscow, 105118
V. Prokhortseva
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: amphil@yandex.ru
俄罗斯联邦, Moscow, 105118
D. Zhigalov
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: amphil@yandex.ru
俄罗斯联邦, Moscow, 105118
D. Zhuk
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: amphil@yandex.ru
俄罗斯联邦, Moscow, 105118
P. Storozhenko
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: amphil@yandex.ru
俄罗斯联邦, Moscow, 105118
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