Thin Films of Cobalt(II) Clathrochelate for Molecular Spintronic Devices

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The possibility of preparing thin films of cobalt(II) cage complex (clathrochelate) that undergoes a temperature-induced spin transition by thermal sublimation was demonstrated using UV spectroscopy. The films were more uniform and more thermally stable than the films formed by centrifugation of the solution on a substrate surface. In combination with scanning electron microscopy data, this revealed the dependence of the spin transition temperature on the method of film preparation and dependence of the supramolecular organization in the films on the substrate material, indicating that transition metal clathrochelates show the spinterface effect at the interface with a metal electrode. In addition to the possibility of controlling the magnetic properties of this unique class of coordination compounds by molecular design methods, this effect opens up broad opportunities for creating molecular spintronic devices with characteristics tailored for the researcher requirements.

作者简介

I. Zlobin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia;
Moscow Institute of Physics and Technology, Dolgoprudny, Moscow oblast, Russia

Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Московская область, Долгопрудный,

R. Aisin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia;
Moscow Institute of Physics and Technology, Dolgoprudny, Moscow oblast, Russia

Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Московская область, Долгопрудный,

A. Sinel’nikov

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia;
Moscow Institute of Physics and Technology, Dolgoprudny, Moscow oblast, Russia

Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Московская область, Долгопрудный,

V. Novikov

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia;
Moscow Institute of Physics and Technology, Dolgoprudny, Moscow oblast, Russia

Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Московская область, Долгопрудный,

Yu. Nelyubina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia;
Moscow Institute of Physics and Technology, Dolgoprudny, Moscow oblast, Russia

编辑信件的主要联系方式.
Email: unelya@ineos.ac.ru
Россия, Москва; Россия, Московская область, Долгопрудный,

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版权所有 © И.С. Злобин, Р.Р. Айсин, А.Н. Синельников, В.В. Новиков, Ю.В. Нелюбина, 2023