The First Example of Dicubane Nickel(II) Complex in the Series of Unsymmetrically Substituted Diketones

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

The first homometal dicubane nickel(II) complex based on unsymmetrically substituted 1,3-diketone (1,1,1-trifluoro-4-(2-methoxyphenyl)butan-2,4-dione) was synthesized and studied by X-ray diffraction using synchrotron radiation (CCDC no. 861889). In the crystal of the complex, nickel atoms are joined into tetrahedra sharing a common vertex with Ni…Ni distances of 3.026–3.127 A; the geometry is completed to a distorted dicubane by μ3-bridging oxygen atoms of the hydroxyl groups. The coordination environment of each metal center is a distorted octahedron, the ligand is deprotonated and performs a bidentate function, forming six-membered chelate rings.

全文:

受限制的访问

作者简介

L. Khamidullina

Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B.N. Yeltsin

Email: puzyrev@ios.uran.ru
俄罗斯联邦, Yekaterinburg; Yekaterinburg

I. Puzyrev

Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: puzyrev@ios.uran.ru
俄罗斯联邦, Yekaterinburg

P. Dorovatovsky

Kurchatov Institute

Email: puzyrev@ios.uran.ru
俄罗斯联邦, Moscow

V. Khrustalev

Peoples' Friendship University of Russia; Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: puzyrev@ios.uran.ru
俄罗斯联邦, Moscow; Moscow

A. Pestov

Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B.N. Yeltsin

Email: puzyrev@ios.uran.ru
俄罗斯联邦, Yekaterinburg; Yekaterinburg

参考

  1. Shiga T., Newton G.N., Oshio H. // Dalton Trans. 2018. V. 47, № 22. P. 7384.
  2. Kirillov A.M., Kirillova M. V., Pombeiro A.J.L. // Coord. Chem. Rev. 2012. V. 256. № 23–24. P. 2741.
  3. Ungur L., Lin S.Y., Tang J. et al. // Chem. Soc. Rev. 2014. V. 43. № 20. P. 6894.
  4. Nesterov D.S., Nesterova O. V., Pombeiro A.J.L. // Coord. Chem. Rev. 2018. V. 355. P. 199.
  5. Wang K., Gao E. // Anticancer Agents Med. Chem. 2014. V. 14. № 1. P. 147.
  6. Muetterties E.L., Rhodin T.N., Band E. et al. // Chem. Rev. 1979. V. 79. № 2. P. 91.
  7. Zhao Q., Harris T.D., Betley T.A. // J. Am. Chem. Soc. 2011. V. 133. № 21. P. 8293.
  8. Sanz S., O´Connor H.M., Martí-Centelles V. et al. // Chem. Sci. 2017. V. 8. № 8. P. 5526.
  9. Horiuchi S., Tachibana Y., Yamashita M. et al. // Nat. Commun. 2015. V. 6. Art. 6742.
  10. Zaleski C.M., Tricard S., Depperman E.C., et al. // Inorg. Chem. 2011. V. 50. № 22. P. 11348.
  11. Engelhardt L.P., Muryn C.A., Pritchard R.G. et al. // Angew. Chem. Int. Ed. 2008. V. 47. № 5. P. 924.
  12. Schäfer B., Greisch J.F., Faus I. et al. // Angew. Chem.Int. Ed. 2016. V. 55. № 36. P. 10881.
  13. Shvachko Y.N., Starichenko D. V., Korolev A. V. et al. // Inorg. Chim. Acta. 2018. V. 483. P. 480.
  14. Murrie M., Stoeckli-Evans H., Güdel H.U. // Angew. Chem.. Int. Ed. 2001. V. 40, № 10. P. 1957.
  15. Aromí G., Parsons S., Wernsdorfer W. et al. // Chem. Commun. 2005. № 40. P. 5038.
  16. Keene T.D., Hursthouse M.B., Price D.J. // New. J. Chem. 2004. V. 32. № 9. P. 1.
  17. Petit S., Neugebauer P., Pilet G. et al. // Inorg. Chem. 2012. V. 51. № 12. P. 6645.
  18. Dong W.K., Zhu L.C., Dong Y.J. et al. // Polyhedron. 2016. V. 117. P. 148.
  19. Mameri S. // Inorg, Chim. Acta. 2017. V. 455. P. 231.
  20. Kuznetsova O. V., Fursova E.Y., Letyagin G.A. et al. // Russ. Chem. Bull. 2018. V. 67, № 7. P. 1202.
  21. Hameury S., Kayser L., Pattacini R. et al. // ChemPlusChem. 2015. V. 80 № 8. P. 1312.
  22. Khamidullina L.A., Puzyrev I.S., Glukhareva T. V. et al. // J. Mol. Struct. 2019. V. 1176. P. 515.
  23. Battye T.G.G., Kontogiannis L., Johnson O. et al. // Acta Crystallogr. D. 2011. V. 67, № 4. P. 271.
  24. Evans P. // Acta Crystallogr. D. 2006. V. 62. № 1. P. 72.
  25. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.

补充文件

附件文件
动作
1. JATS XML
下载
2. Scheme 1

下载 (179KB)
索引源数据
3. Fig. 1. Molecular structure of complex I in thermal ellipsoids of 30% probability. Hydrogen atoms and the solvated water molecule are not depicted. For disordered groups only the major components are given

下载 (403KB)
索引源数据
4. Fig. 2. Structure of the inorganic core and coordination polyhedron of complex I according to PCA data

下载 (331KB)
索引源数据
5. Fig. 3. Coordination environment of the peripheral metal centre in complex I according to PCA data

下载 (149KB)
索引源数据
6. Fig. 1

下载 (9KB)
索引源数据
7. Fig. 2

下载 (9KB)
索引源数据
8. Fig. 3

下载 (15KB)
索引源数据
9. Fig. 4. FT-IR spectrum of complex I

下载 (89KB)
索引源数据

版权所有 © Российская академия наук, 2024