Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties

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Complexes [PdL2Cl2] (I) and [PdL2Вr2] (II) (L is 5-acetyl-6-methyl-4-(3-nitrophenyl)-1,2,3,4-tetrahydropyrimidine-2-thione) are synthesized and characterized by spectral methods (1Н, 13С NMR and IR spectroscopy). The crystal structure of complex I is determined (CIF file ССDС no. 2233053) in which the palladium atom is coordinated by two halide ions and two sulfur atoms of two ligands L in a distorted square planar geometry. The catalytic activity of the synthesized palladium(II) complexes in the model epoxidation of allyl alcohol is estimated in comparison with the catalytic activity of the corresponding palladium halides and titanium-containing zeolite TS-1.

作者简介

A. Kuzovlev

Moscow State University; Tyumen State University

编辑信件的主要联系方式.
Email: a.s.kuzovlev@gmail.com
俄罗斯联邦, Moscow; Tyumen

N. Gordeeva

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
俄罗斯联邦, Moscow

Zh. Pastukhova

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
俄罗斯联邦, Moscow

V. Chernyshev

Moscow State University; Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: a.s.kuzovlev@gmail.com
俄罗斯联邦, Moscow; Moscow

G. Buzanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: a.s.kuzovlev@gmail.com
俄罗斯联邦, Moscow

S. Dunaev

Moscow State University

Email: a.s.kuzovlev@gmail.com
俄罗斯联邦, Moscow

L. Bruk

Russian Technological University (MIREA)

Email: a.s.kuzovlev@gmail.com
俄罗斯联邦, Moscow

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