Trimethylammonium dichloro-hexachlorotellurate(IV): crystal structure and features of non-covalent interactions of Cl···Cl

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By the reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of chlorine gas in concentrated hydrochloric acid, supramolecular dichloro-hexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I) was obtained, the structure of which was determined by X-ray diffraction. Based on elemental and X-ray phase analysis data, a conclusion was made about the limited stability of the resulting compound. The features of non-covalent Cl···Cl interactions in the crystal structure of this compound were studied by Raman spectroscopy (Raman).

作者简介

A. Usoltsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: usoltsev@niic.nsc.ru
Россия, Новосибирск

A. Sonina

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: usoltsev@niic.nsc.ru
Россия, Новосибирск

N. Korobeinikov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia; Novosibirsk State University, Novosibirsk, Russia

Email: usoltsev@niic.nsc.ru
Россия, Новосибирск; Россия, Новосибирск

S. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia;Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

编辑信件的主要联系方式.
Email: adonin@niic.nsc.ru
Россия, Новосибирск; Россия, Новосибирск

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