Influence of conditions for modification of oxidized carbon nanotubes on the catalytic activity and selectivity in the oxygen reduction reaction to hydrogen peroxide

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Catalysts of cathodic hydrogen peroxide synthesis were obtained from pre–oxidized with nitric acid multiwalled carbon nanotubes (MWCNTs), followed by hydrogen reduction in a temperature range of 300–500°C. Evaluation of physico–chemical properties of catalysts reveals the synthesis method used allowed for controlled changes composition of oxygen groups on surface without change of MWCNTs structure and morphology. Investigation of catalytic activity in cathodic process for production of hydrogen peroxide demonstrated the sample prepared by hydrogen reduction at 300°C with oxygen content of 5.2 at. % (based on XPS data) had the highest efficiency. The sample produced hydrogen peroxide with rate of 0.34 mol/(g·h) and Faradaic efficiency of 78%. Increase in reduction temperature more than 300°C resulted in decrease in rate of accumulation Н2О2 without severe change Faradaic efficiency.

Авторлар туралы

N. Maltseva

Novosibirsk State University; Boreskov Institute of Catalysis SB RAS

Хат алмасуға жауапты Автор.
Email: maltseva.n.v@catalysis.ru
Ресей, Novosibirsk; Novosibirsk

S. Moseenkov

Boreskov Institute of Catalysis SB RAS

Email: maltseva.n.v@catalysis.ru
Ресей, Novosibirsk

M. Lebedeva

Novosibirsk State University; Boreskov Institute of Catalysis SB RAS

Email: maltseva.n.v@catalysis.ru
Ресей, Novosibirsk; Novosibirsk

D. Kozlov

Novosibirsk State University; Boreskov Institute of Catalysis SB RAS

Email: maltseva.n.v@catalysis.ru
Ресей, Novosibirsk; Novosibirsk

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