Electrocatalytic Properties of Water-Soluble Nickel(II) and Copper(II) Phthalocyaninates in the Oxidation Reaction of Hydroxide Ions

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Abstract

In this work, the electrochemical and electrocatalytic behavior of gold electrodes modified with nickel(II) (NiPc) and copper(II) (CuPc) tetra-4-sulfophthalocyaninates in an aqueous alkaline solution was studied using cyclic voltammetry. A comparative assessment of the electrocatalytic activity of the studied metal phthalocyaninates in the oxidation reaction of hydroxide ions with the formation of molecular oxygen is given, and a comparison is made with literature data.

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About the authors

M. A. Kovanova

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: mariia.a.kovanova@gmail.com
Russian Federation, Ivanovo

P. D. Derbeneva

Ivanovo State University of Chemistry and Technology

Email: mariia.a.kovanova@gmail.com
Russian Federation, Ivanovo

A. S. Postnov

Ivanovo State University of Chemistry and Technology

Email: mariia.a.kovanova@gmail.com
Russian Federation, Ivanovo

T. V. Tikhomirova

Ivanovo State University of Chemistry and Technology

Email: mariia.a.kovanova@gmail.com
Russian Federation, Ivanovo

A. S. Vashurin

Ivanovo State University of Chemistry and Technology

Email: mariia.a.kovanova@gmail.com
Russian Federation, Ivanovo

O. I. Koifman

Ivanovo State University of Chemistry and Technology

Email: mariia.a.kovanova@gmail.com
Russian Federation, Ivanovo

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2. Fig. 1. Structural formulae of tetra-4-sulfophthalocyaninates of nickel(II) and copper(II)

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3. Fig. 2. CVA curves recorded at unmodified gold electrode (curve 1) and at CuPc (2) and NiPc (3) modified electrodes in Na2HPO4/NaOH buffer solution at pH 12 (25°C, background electrolyte - 0.1 M TBAP) containing 0.01 M NaOH (25°C) at a linear sweep rate of 100 mV/s potential

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4. Fig. 3. SEM images of the surfaces of unmodified (a) and modified NiPc (b) gold electrodes

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5. Fig. 4. SEM images of the surface of the NiPc modified gold electrode taken at different magnifications: (a) 20 μm; (b) 5 μm; (c) 1 μm

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6. Fig. 5. (a) Anodic voltammetry branches of hydroxide ion oxidation at the gold electrode modified NiPc in Na2HPO4/NaOH buffer solution at pH 12 (25.0°C, background electrolyte - 0.1 M TBAP) at different scanning speeds: 10 mV/s (1), 25 mV/s (2), 50 mV/s (3), 75 mV/s (4), 100 mV/s (5). (b) Dependence of lgIp - lgν for NiPc anodic currents. (c) Dependence of Ip - ν0.5 for NiPc anodic currents. (d) Relationship between Ipv-1/2 and ν. (e) Relationship between Ep and lgν

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