Kinetics of Catalytic Oxidation of Oleic Acid Methyl Ester

D. Yu. Yhshchenko; Ющенко Д. Ю.; Z. P. Pai; Пай З. П.; U. V. Uchenova; Ученова Ю. В.; T. B. Khlebnikova; Хлебникова Т. Б.

doi:10.31857/S0453881123030127

Kinetics of Catalytic Oxidation of Oleic Acid Methyl Ester

Авторлар: Yhshchenko D.Y.¹, Pai Z.P.¹, Uchenova U.V.¹, Khlebnikova T.B.¹
Мекемелер:
1. Boreskov Institute of Catalysis SB RAS
Шығарылым: Том 64, № 3 (2023)
Беттер: 298-304
Бөлім: ARTICLES
URL: https://medjrf.com/0453-8811/article/view/660277
DOI: https://doi.org/10.31857/S0453881123030127
ID: 660277

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

The results of studying the kinetics of the reaction of catalytic oxidation of oleic acid methyl ester with hydrogen peroxide in a two-phase system (aqueous phase-organic phase) in the presence of a bifunctional catalyst of the composition [(Octⁿ)₃NMe]₃{PO₄[WO(O₂)₂]₄} are presented. For the selected reaction conditions, the first orders of catalyst, substrate and oxidizer are established. The value of the activation energy for the temperature range 313–353 K is 47 ± 3 kJ/mol, and the pre-exponential multiplier is (6.0 ± 0.3) × 10⁷ L² mol^–2 min^–1.

Негізгі сөздер

oleic acid, oleic acid methyl ester, epoxides, tungsten peroxocomplexes, hydrogen peroxide, homogeneous and heterogeneous catalysis

Әдебиет тізімі

Cerone M., Smith T.K. // Front. Nutr. 2021. V. 8. P. 1.
Biermann U., Bornscheuer U.T., Feussner I., Meier M.A.R., Metzger J.O. // Angew. Chem. Int. Ed. 2021. V. 60. № 37. P. 20144.
Отопкова К.В., Есипович А.Л., Канаков Е.А., Чарыкова Т.А., Байдаченко В.Е., Рябова Т.А. // Кинетика и катализ. 2022. V. 63. № 6. P. 749.
Singh H., Ali A. // Кинетика и катализ. 2022. V. 63. № 6. P. 772.
Belousov A.S., Esipovich A.L., Kanakov E.A., Otopkova K.V. // Sust. Energy Fuels. 2021. V. 5. № 18. P. 4512.
Wypych G. // PVC Degrad. Stab. 2015. P. 287.
Meng Y., Taddeo F., Aguilera A.F., Cai X., Russo V., Tolvanen P., Leveneur S. // Catalysts. 2021. V. 11. № 7. P. 765.
Swern D., Findley T.W., Scanlan J.T. // J. Am. Chem. Soc. 1944. V. 66. № 11. P. 1925.
Musik M., Janus E., Pełech R., Sałaciński Ł. // Catalysts. 2021. V. 11. № 9. P. 1058.
Есипович А.Л., Белоусов А.С., Канаков Е.А., Миронова В.Ю., Рогожин А.Е., Данов С.М., Воротынцев А.В., Макаров Д.А. // Кинетика и катализ. 2019. V. 60. № 1. P. 66.
Pai Z.P., Chesalov Y.A., Berdnikova P. V, Uslamin E.A., Yushchenko D.Y., Uchenova Y. V, Khlebnikova T.B., Baltakhinov V.P., Kochubey D.I., Bukhtiyarov V.I. // Appl. Catal. A: Gen. 2020. V. 604. P. 117786.
Khlebnikova T.B., Pai Z.P., Fedoseeva L.A., Mattsat Y.V. // React. Kinet. Catal. Lett. 2009. V. 98. № 1. P. 9.
Pai Z.P., Khlebnikova T.B., Mattsat Y.V., Parmon V.N. // React. Kinet. Catal. Lett. 2009. V. 98. № 1. P. 1.
Maiti S.K., Snavely W.K., Venkitasubramanian P., Hagberg E.C., Busch D.H., Subramaniam B. // Ind. Eng. Chem. Res. 2019. V. 58. № 7. P. 2514.
Yushchenko D.Y., Pai Z.P., Khlebnikova T.B. // Catal. Lett. 2022. V. 152. № 7. P. 2025.
Sheldon R.A., Arends I.W.C.E., Dijksman A. // Catal. Today. 2000. V. 57. № 1–2. P. 157.