On the Possibility of Thermokinetic Oscillations in the Reaction of Methane Oxidation on Nickel

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The paper demonstrates the possibility of occurrence of thermokinetic oscillations during the methane oxidation on a nickel industrial catalyst at real values of the parameters. It is shown that reaction rate oscillations can originate under the conditions of short contact times and in the region where periodic oxidation–reduction processes do not occur. The origin of these thermokinetic oscillations is the periodic blocking of the surface with carbon and its cleaning by removing carbon from the catalyst surface.

Авторлар туралы

N. Peskov

Moscow State University named after M.V. Lomonosov, Faculty of Computational Mathematics and Cybernetics

Email: slinko@polymer.chph.ras.ru
Russia, 119992, Moscow, Leninskie Gory

M. Slinko

Semenov Institute of Chemical Physics of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: slinko@polymer.chph.ras.ru
Russia, 119991, Moscow, Kosygin str., 4

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