XPS Study of the Preparation of Single-Site Catalysts Based on Ir(I) and Rh(I) Complexes Immobilized on a SiO2 Surface Using a P-Containing Linker

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Abstract

Samples of model single-site iridium and rhodium catalysts were synthesized by immobilization of complexes [Ir(COD)(IMes)Cl] and [Rh(COD)(IMes)Cl], where COD is cyclooctadiene-1,5 and IMes is 1,3‑bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, on the surface of silicon dioxide modified with a linker containing diphenylphosphine group (Ph2P). Silicon plates with a flat surface covered with a layer of natural oxide 1–3 nm thick, Si-SiO2(nat), or with a specially grown SiO2 film (∼300 nm), Si-SiO2(ox), were used as supports. The chemical compositions of the surface of the modified silicon plates and samples of model catalysts were characterized by XPS. Based on these XPS studies, a tentative conclusion was made about the coordination of immobilized complexes to the SiO2 surface. Catalyst samples were tested in the gas-phase hydrogenation of propene with parahydrogen.

About the authors

M. Yu. Smirnov

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: smirnov@catalysis.ru
Russia, 630090, Novosibirsk, Acad. Lavrentiev pr., 5

L. M. Kovtunova

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: smirnov@catalysis.ru
Russia, 630090, Novosibirsk, Acad. Lavrentiev pr., 5

A. V. Kalinkin

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: smirnov@catalysis.ru
Russia, 630090, Novosibirsk, Acad. Lavrentiev pr., 5

I. V. Skovpin

International Tomography Center, Siberian Branch, Russian Academy
of Sciences

Email: smirnov@catalysis.ru
Russia, 630090, Novosibirsk, Institutskaya st., 3A

I. V. Koptyug

International Tomography Center, Siberian Branch, Russian Academy
of Sciences

Email: smirnov@catalysis.ru
Russia, 630090, Novosibirsk, Institutskaya st., 3A

V. I. Bukhtiyarov

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: smirnov@catalysis.ru
Russia, 630090, Novosibirsk, Acad. Lavrentiev pr., 5

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