Stability of Polymer Composite Membranes Based on Fluorinated Polysiloxanes under Tropical Conditions

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Resumo

One of the key objectives of membrane technology is to improve the resistance to fouling (fouling) and degradation of membrane surface. In this work, the stability properties of selective layer based on fluorinated polysiloxanes were investigated during exposure for 6 months at climatic sites in Vietnam. Three composite membranes on MFFC-1 microfiltration substrate with selective layers: 1) polydecimethylsiloxane (C10), 2) copolymer of C10 and polysiloxane with trifluoroalkylacrylate side group (C10-F3), 3) copolymer of C10 and polysiloxane with perfluorooctyl side group (C10-PFO) were investigated in this work. A comparison of changes in the composition and surface properties of the selective layer, as well as gas transport properties before and after exposure to the test sites was analyzed. It is shown that for membranes based on fluorine-containing polysiloxanes (C10-F3 and C10-PFO) less clogging and degradation of the selective layer polymer is observed. For sample C10, destruction of side alkyl fragments and increase in the concentration of oxygen atoms on the surface of the selective layer was observed, including due to the deposition of microalgae. Membranes C10-F3 showed the greatest stability of gas permeability by CO2 and N2 (change not more than 10%) and the least oxidative degradation.

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Sobre autores

T. Rohmanka

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Email: evgrushevenko@ips.ac.ru
Rússia, 29 Leninsky pr., Moscow, 119991

E. Dmitrieva

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Email: evgrushevenko@ips.ac.ru
Rússia, 29 Leninsky pr., Moscow, 119991

T. Anokhina

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Email: evgrushevenko@ips.ac.ru
Rússia, 29 Leninsky pr., Moscow, 119991

Yu. Kostina

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Email: evgrushevenko@ips.ac.ru
Rússia, 29 Leninsky pr., Moscow, 119991

E. Grushevenko

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Autor responsável pela correspondência
Email: evgrushevenko@ips.ac.ru
Rússia, 29 Leninsky pr., Moscow, 119991

Thanh Long Hoang

Southern Branch of Joint Vietnam-Russia Tropical Science and Technology Research Center

Email: evgrushevenko@ips.ac.ru
Vietnã, Ho Chi Minh City 740500

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2. Fig. 1. Laboratory setup for measuring the gas permeability of a mixture.

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3. Fig. 2. SEM images of the surface of the selective layer of membranes M–C10, M–F3 and M–PFO before and after long-term exposure to the climate of Vietnam.

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4. Fig. 3. Optical images of M-C10, M-F3 and M-PFO membranes before and after long-term exposure at the Con Zo and Hoa Lac Scientific Research Institute and the Dam Bai Scientific Research Institute.

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5. Fig. 4. Changes in the contact angle of wetting of the surface of the selective layer of composite membranes M–C10, M–F3 and M–PFO before and after exposure for 6 months at the testing stations of the Tropcenter.

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6. Fig. 5. IR-ATR spectra of the initial M-10 membrane (curve 1) and M-10 membranes after exposure to the KIS Hoa Lac (curve 2), Kon Zo (curve 3) and MNIIS Dam Bai (curve 4) in the middle region of the IR spectrum (a), in the region of absorption of C=O bonds (b) and vibrations of the skeleton of CH bonds at – (СН₂)₄₊ – (c). The inset shows the region of absorption of stretching vibrations of CH and associated NH bonds.

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7. Fig. 6. IR-ATR spectra of the initial M–F3 membrane (curve 1) and M–F3 membranes after exposure to the Khoa Lak (curve 2), Kon Zo (curve 3) and Dam Bai (curve 4) KIS in the middle region of the IR spectrum (a), in the region of absorption of C=O bonds (b) and vibrations of the skeleton of CH bonds at – (СН₂)₄₊ – (c). The inset shows the region of absorption of stretching vibrations of CH and associated NH bonds.

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8. Fig. 7. IR-ATR spectra of the initial M–PFO membrane (curve 1) and M–PFO membranes after exposure to the Khoa Lak (curve 2), Kon Zo (curve 3) and Dam Bai (curve 4) KIS in the middle region of the IR spectrum (a), in the region of absorption of C=O bonds (b) and vibrations of the skeleton of CH bonds at –(СН₂)₄₊ – (c). The inset shows the absorption region of stretching vibrations of CH and associated NH bonds.

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9. Fig. 8. Relative content of CH₂/CH₃ groups in polysiloxane membranes depending on the climatic conditions of Vietnam, % of the original.

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10. Fig. 9. Data on changes in insolation (a) and air humidity (b) in the period from June (6) to November (11) at the climatic sites of Vietnam.

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11. Fig. 10. Change in the integral intensity in the absorption region of C=O bonds of various functional groups in the IR-ATR spectra of membranes before and after exposure at the Tropcenter test stations.

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12. Fig. 11. Relative change in permeability of CO₂ (a), N₂ (b) and ideal selectivity CO₂/N₂ (c) after exposure at the Tropcenter test stations.

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